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For emails to be sent and received by a recipient, email address is required.
Email address is made up of local part, @ symbol, then SMTP domain name. Order can be important if you have many email address policies.
Similarly, both email address policy is applied to all recipients, so becomes secondary.
The Update-Email Address Policy cmdlet queries for all recipients that match the specified email address policy and saves the objects to Active Directory.
Use the Update-Email Address Policy cmdlet after you use the Set-Email Address Policy cmdlet to apply all changes.
For more information about the Set-Email Address Policy cmdlet, see Set-Email Address Policy.
Before you configure email address policy in Exchange 2016, the associated SMTP domain name must be configured as accepted domain name. If you open the properties of a mailbox, you will see is now secondary SMTP domain name.
Because email address policy has priority of 1 so it wins.
You identify the domain controller by its fully qualified domain name (FQDN).